If you are creating just a single pulse use the config pulse vis
For the 33220A, if you are creating an ARB waveform you can only set the time for each point on the front panel. There is no way to set the time for individual points via programming.
The way I get around it is to create numerous points to get my desired signal. For example, I have a pulse train of 1 usec low then 3 usec high then 2 usec low. I would create a point = 1 usec then use that to build my signal. I would have used a total of 6 points to create my waveform.
To set point rate you will need to set the freq of the arb.
I think this is the formula or a variation of it
Frequency = (1/point rate in usecs)/total #of points in waveform
I use this method to create waveforms to validate my companies comm protocols.
Brian