The fastest way is to use standard c sprintf command.
The syntax for your present problem is:
sprintf (string, "%05.0f", floatVal * 100.0);
if floatVal = 1.23 => string = "00123".
In this case sprintf performs the usual rounding, so that if floatVal = 1.236 string will be "00124".
In case you won't use sprintf, the same can be achieved (with slightly different formatting code) with Fmt function in the Formatting and I/O Library that ships with CVI.
Hope this helps
Roberto